Research: Charge Density Waves


  ErTe3
It is generally accepted that magnetic interactions are important in cuprate and Fe-based superconductors. The parent phase in both materials is antiferromagnetic; magnetic resonances are observed via neutron scattering in the superconducting state in both families; and the pairing symmetries in both families (including the multiplicity of pairing symmetries in Fe-based superconductors) can be naturally understood in terms of the dominant spin fluctuations. However, it is becoming increasingly apparent that charge ordered states are also present in the phase diagrams of both families, raising broader questions about the inter-relation of these other types of ordered states and their fluctuations with superconductivity. A large part of our research in the field of Fe-based superconductors is directed towards understanding the effects of nematic order and nematic fluctuations on the emergent superconductivity. A second area of study, more relevant to (motivated by) the cuprates than the Fe-based superconductors, relates to understanding the role(s) played by charge density wave (CDW) correlations and fluctuations in tetragonal materials, including effects due to the presence of disorder. Here we seek model systems to explore these effects in isolation from any incipient magnetic order. More broadly, there are many open questions simply regarding CDW formation in quasi-2D materials, including the relative importance of electron-phonon coupling and Fermi surface nesting, motivating a careful investigation of such systems.

Over the last few years we have shown that the rare earth (R) tri-tellurides RTe3 are just such model materials, hosting a unidirectional or, in some cases, bidirectional, incommensurate CDW. As such, they provide us with a unique opportunity to study the electronic structure of a pseudo-tetragonal material deep in such a state, to understand the driving force behind the instability, and indeed to explore how that state is perturbed by disorder.

Most recently, we have demonstrated how anisotropic strain can shift the balance between the two orthogonal unidirectional CDW phases in ErTe3. For large positive values of the anisotropic strain one CDW phase is favored, and for large negative values of the strain the other (orthogonal) CDW phase is favored (Figure). A glide plane in the crystal structure means that the bicritical point which is defined by the meeting of these two distinct phase boundaries does not happen at any symmetry-dictated value of the strain or of the in-plane lattice parameters – the material is fundamentally orthorhombic. However, as we revealed experimentally via elastoresistivity measurements, the material exhibits a remarkable emergent tetragonal symmetry proximate to this bicritical point. This behavior is intimately linked to the critical behavior. Of note in its own right, these observations fall within a wider context of materials for which non-symmetry-enforced degeneracies appear to play a crucial role in the emergent properties, providing new insights into possible mechanisms that might favor such effects.
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Fisher Research Group
Geballe Laboratory for Advanced Materials
Dept. of Applied Physics
Stanford University
CA 94305-4045
Last Updated: Nov 25th 2024